Organic Letters
Letter
(11) Terao, J.; Oda, A.; Ikumi, A.; Nakamura, A.; Kuniyasu, H.;
Kambe, N. Angew. Chem., Int. Ed. 2003, 42, 3412.
(12) Iwasaki, T.; Min, X.; Fukuoka, A.; Kuniyasu, H.; Kambe, N.
ASSOCIATED CONTENT
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S
* Supporting Information
Angew. Chem., Int. Ed. 2016, 55, 5550.
The Supporting Information is available free of charge on the
(13) A similar complex was synthesized by the reaction of a Ni(0)
complex with PhLi and divinylcyclobutane, although the details of
characterization as well as the reactivities have not been documented:
(a) Holle, S.; Jolly, P. W.; Mynott, R.; Salz, R. Z. Naturforsch., B: J.
Chem. Sci. 1982, 37, 675. (b) Jonas, K.; Kruger, C. Angew. Chem., Int.
Ed. Engl. 1980, 19, 520. Also see ref 12 for preliminary isolation of a
similar complex.
Additional results, procedures, characterization data, and
Crystallographic data for 1′ (CIF)
̈
(14) (a) Posner, G. H. Chem. Rev. 1986, 86, 831. (b) Armstrong, R.
W.; Combs, A. P.; Tempest, P. A.; Brown, S. D.; Keating, T. A. Acc.
AUTHOR INFORMATION
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Chem. Res. 1996, 29, 123. (c) Bienayme, H.; Hulme, C.; Oddon, G.;
Corresponding Authors
Schmitt, P. Chem. - Eur. J. 2000, 6, 3321.
Notes
(15) CCDC-1478800 contains the supplementary crystallographic
data for this paper. These data can be obtained free of charge from the
The authors declare no competing financial interest.
(17) Representative reviews: (a) Amii, H.; Uneyama, K. Chem. Rev.
2009, 109, 2119. (b) Ahrens, T.; Kohlmann, J.; Ahrens, M.; Braun, T.
Chem. Rev. 2015, 115, 931.
(18) Negishi coupling: (a) Nakamura, Y.; Yoshikai, N.; Ilies, L.;
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Ogoshi, S. Chem. - Eur. J. 2014, 20, 2040. Suzuki coupling: (c) Schaub,
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(d) Cargill, M. R.; Sandford, G.; Tadeusiak, A. J.; Yufit, D. S.; Howard,
J. A. K.; Kilickiran, P.; Nelles, G. J. Org. Chem. 2010, 75, 5860.
ACKNOWLEDGMENTS
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This work was supported by JSPS KAKENHI Grants
JP25248025, JP16H06039, JP25105734, and JP16H01150.
We thank JSPS for the Japanese−German Graduate Externship.
T.I. thanks The Sumitomo Foundation.
(e) Breyer, D.; Braun, T.; Klaring, P. Organometallics 2012, 31, 1417.
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