Inorganic Chemistry p. 2345 - 2349,2347,2349 (1978)
Update date:2022-08-29
Topics:
Card, Roger J.
Neckers, Douglas C.
Poly(styryl)bipyridine, 1, is produced from the reaction of lithiated polystyrene with bipyridine in tetrahydrofuran. Under our conditions, bipyridine becomes bound to 10-15% of the phenyl residues. The reaction of 1 with a variety of transition-metal salts can be carried out in a variety of swelling solvents and results in formation of polymer-bound bipyridine transition-metal complexes. The extent of metal incorporation depends on solvent, metal ion concentration, and the identity of the metal species. Zerovalent metal complexes such as&24C5;-Ph-bpy-M(CO)4 (M = Cr, Mo, W) are readily prepared from the reaction of 1 with the metal hexacarbonyl complexes. (Poly(styryl)bipyridyl)palladium acetate is an active catalyst for the hydrogenation of olefins at ambient pressure and temperature. It can also be used to catalyze the acetoxylation of benzene; however, the percent conversion in this case is rather low.
View MoreHangzhou Reb Technology Co., Ltd.
Contact:571-81902596
Address:Room 502,Buil.5,No.1 Xi Yuan Rd. The West Lake Science&Technology Park, Hangzhou,Zhejiang,China.
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Weifang Ocean Trading Co., Ltd.
Contact:+86-536-2081155
Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Zhengzhou Yuanli Biological Technology Co., Ltd.
Contact:+86-371-67897870/67897895
Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Linyi Shengxin Pharmaceutical R&D Co., Ltd
Contact:+86-18653953873
Address:West First of Yufeng Road, Yishui County
Doi:10.1080/00304940009356755
(2000)Doi:10.1080/00397919908085967
(1999)Doi:10.1039/jr9600001151
(1960)Doi:10.1016/S0022-328X(00)91869-2
(1975)Doi:10.1016/j.poly.2019.01.043
(2019)Doi:10.1002/jccs.201200531
(2013)