Nucleosides, nucleotides and nucleic acids p. 297 - 327 (2000)
Update date:2022-08-28
Topics:
Daluge, Susan M.
Martin, Michael T.
Sickles, Barry R.
Livingston, Douglas A.
Ziagen, (1S, cis)-4-[2-amino-6-(cyclopropylamino)-9H-purin-9-yl]-2- cyclopentene-1-methanol, was synthesized from (1S,4R)-azabicyclo[2.2.1]hept- 5-en-3-one by efficient processes which bypass problematic steps in earlier routes. 2-Amino-4,6-dichloro-5-formamidopyrimidine is a key intermediate which makes possible an efficient construction of the purine from a chiral cyclopentenyl precursor.
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