Journal of Physical Organic Chemistry p. 399 - 402 (1994)
Update date:2022-08-11
Topics:
Dalmagro, Jacir
Yunes, Rosendo A.
Simionatto, Edesio Luiz
The reaction of nitrosobenzene with aniline, to give azobenzene, in basic conditions was studied.It was shown that the reaction exhibits general base catalysis by different buffers giving a Broensted coefficient β = 0.318.As in previous studies, a two-step process with a first step of attack of aniline on nitrosobenzene to give an addition intermediate and a second step of dehydration of this intermediate is proposed to interpret the mechanism of the reaction.The analysis of the Broensted relationship and of the intermediate of the reaction led to the suggestion that hydroxide ion catalyses the reaction by a mechanism of general base catalysis in the dehydration step.
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