Heterocycles p. 1921 - 1928 (1999)
Update date:2022-08-16
Topics:
Kim, Byeong Hyo
Kim, Tae Kyu
Cheong, Jae Wook
Lee, Sang Woo
Jun, Young Moo
Baik, Woonphil
Lee, Byung Min
Under the mild condition, allyl bromide/Zn mediated reductive N,O- diallylation of nitrobenzene was observed. In case of o-nitroarenes such as 2-nitrobenzaldehyde derivatives, 2'-nitroacetophenone, and N-(2- nitrobenzylidene)anilines, reductive cyclizations were accomplished in good to excellent yields. Synthesis and mechanistic details are discussed.
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