Inorganica Chimica Acta p. 93 - 99 (2019)
Update date:2022-08-11
Topics:
Moraes, Leonardo C.
de Souza, Gilmar P.
Fajardo, Humberto V.
Luz, Sulusmon C.
álvarez, Eleuterio
Lloret, Francesc
Ribeiro-Viana, Renato M.
Rojo, Javier
Stumpf, Humberto O.
Figueiredo, Rute C.
Corrêa, Rodrigo S.
A novel tetrameric tetra[O-((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)]-pentaerythritol (TBTP) has been synthesized using click chemistry strategy. TBTP was characterized and used as ligand to form new Cu(II) complexes, forming 1-D coordination polymers. Two square planar complexes were characterized by single-crystal X-ray diffraction, presenting formula [Cu(TBTP)][Cu(NO3)4] (1) and [Cu(TBTP)](NO3)2 (2). In both structures, a cationic 1-D coordination polymer (CP) has been formed. The CP contain a 1:1 Cu(II)/TBTP ratio with four neutral triazole groups coordinating the Cu(II) center, forming a Cu[sbnd]N bonds ranging 1.988(2)–2.001(2) ?. The study of the magnetic properties of compounds 1 and 2 pointed to an antiferromagnetic behavior for both compounds, defined by inter- and intra-chain dipolar interactions among their metallic centers. In addition, the complex 1 was found to be an efficient catalyst for selective oxidation of aniline to azobenzene under mild reaction conditions.
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Doi:10.1002/bio.3718
(2020)Doi:10.1002/anie.201406190
(2014)Doi:10.1002/jlac.199719970715
(1997)Doi:10.1021/jacs.0c02997
(2020)Doi:10.1248/cpb.35.1817
(1987)Doi:10.1016/j.bmcl.2010.09.128
(2010)