Synthesis p. 744 - 746 (1997)
Update date:2022-08-25
Topics:
Olah, George A.
Klumpp, Douglas A.
N-Silylpyridinium triflates 1a-c have been prepared in excellent yield from the corresponding allyl silanes by reaction with triflic acid followed by pyridine. Compounds 1a-c were used to prepare silyl ethers from alcohols in generally high yield. A convenient procedure has been developed which enables the silylation of alcohols without an aqueous workup in the product isolation.
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