ACS Catalysis
Letter
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complexes show promise for efficient photocatalytic cofactor
regeneration. One means to address these limitations in the
future is by the selection of more photostable QD materials.
ASSOCIATED CONTENT
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S
* Supporting Information
The Supporting Information is available free of charge on the
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FNR expression and isolation; QD synthesis; light-driven
NADPH production; alcohol production by illuminated
QD-FNR; keto acid to alcohol conversion; quantum
yield measurement; QD spectra; calibration curves for
NADPH and alcohol detection; alcohol production
control sample GC traces; quantum yield measurement
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AUTHOR INFORMATION
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Corresponding Author
Notes
(25) Utterback, J.; Wilker, M.; Brown, K.; King, P.; Eaves, J.;
Dukovic, G. Phys. Chem. Chem. Phys. 2015, 17, 5538.
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(27) Grzyb, J.; Bojko, M.; Waloszek, A.; Strzałka, K. Phytochemistry
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The authors declare no competing financial interest.
ACKNOWLEDGMENTS
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(28) Gocke, D.; Nguyen, C. L.; Pohl, M.; Stillger, T.; Walter, L.;
This work was supported by the Laboratory Directed Research
and Development (LDRD) Program at the National Renewable
Energy Laboratory (to K.A.B. and P.W.K.). FNR expression
was supported by the U.S. Department of Energy, Office of
Biological and Environmental Research (BER) (to M.B.).
NREL is a national laboratory of the U.S. Department of
Energy Office of Energy Efficiency and Renewable Energy
operated by the Alliance for Sustainable Energy, LLC.
Nanocrystal synthesis and ligand exchange were supported by
U.S. Department of Energy, Office of Basic Energy Sciences,
Division of Materials Sciences and Engineering under Award
DE-SC0010334 (to M.B.W., H.H, and G.D.).
Muller, M. Adv. Synth. Catal. 2007, 349 (8−9), 1425−1435.
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(29) Lee, S. H.; Nam, D. H.; Kim, J. H.; Baeg, J.-O.; Park, C. B.
ChemBioChem 2009, 10 (10), 1621−1624.
(30) Lee, S. H.; Nam, D. H.; Park, C. B. Adv. Synth. Catal. 2009, 351
(16), 2589−2594.
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