Journal of Physical Chemistry p. 2698 - 2700 (1981)
Update date:2022-08-11
Topics:
Niki, H.
Maker, P. D.
Savage, C. M.
Breitenbach, L. P.
Using the long path FT IR method, we made product studies of the photolysis of n-butyl nitrite (n-C4H9ONO) in ppm concentrations at 700 torr of air and 298 +/- 2 K.Unidentified HO-containing compounds as well as n-butyraldehyde (n-C3H7CHO) were detected.The results provide further evidence for the occurence of the following competitive uni- and bimolecular reaction paths for the ensuing n-butoxy radicals: intramolecular hydrogen-shift isomerization CH3CH2CH2CH2O. -> CH2CH2CH2CH2OH (1), and O2 reaction CH3CH2CH2CH2O. + O2 -> CH3CH2CH2CHO + HO2 (2).From the observed yield of n-C3H7CHO, the relative rate k2
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