RSC Advances
Paper
pH or hydrogen ions are not the only catalytic factors inu- 18 V. Vasudevan and S. H. Mushrif, RSC Adv., 2015, 5, 20756–
encing the glucose conversion to HMF, but also the nature of 20763.
the acid and the addition of certain salts and the existence of 19 S. J. Dee and A. T. Bell, ChemSusChem, 2011, 4, 1166–1173.
certain kinds of anions play a joint role in improving the HMF 20 X. Qi, M. Watanabe, T. M. Aida and R. L. Smith Jr, Cellulose,
yield.
HCl and NaCl were selected as the catalyst and reaction 21 C. Moreau, A. Finiels and L. Vanoye, J. Mol. Catal. A: Chem.,
promoter respectively in the present study, due to the high 2006, 253, 165–169.
selectivity and low price. An impressively high yield of 62.45% of 22 J. N. Chheda, Y. Roman-Leshkov and J. A. Dumesic, Green
HMF and 18.22% of LA were obtained at 140 ꢀC and in 60 min in
Chem., 2007, 9, 342–350.
a H2O/GVL system, in which 0.2 M HCl was used as the catalyst 23 X. Li, Q. Xia, K. Peng, X. Liu, N. Essayem and Y. Wang, Catal.
and 0.1 M NaCl was used as the reaction promoter. A possible Sci. Technol., 2016, 6, 7586–7596.
model for industrial applications was proposed, showing the 24 J. Sun, X. Yuan, Y. Shen, Y. Yi, B. Wang, F. Xu and R. Sun, Ind.
2011, 18, 1327–1333.
´
high potential of such a system in the glucose conversion to
HMF.
Crops Prod., 2015, 70, 266–271.
25 C. Wang, L. Fu, X. Tong, Q. Yang and W. Zhang,
Carbohydr.Res., 2012, 347, 182–185.
26 L. Zhang, H. Yu, P. Wang and Y. Li, Bioresour. Technol., 2014,
151, 355–360.
Acknowledgements
This study was nancially supported by the National Key 27 L. Qi, Y. F. Mui, S. W. Lo, M. Y. Lui, G. R. Akien and
Technology R&D Program of China (No. 2015BAD15B06),
I. T. Horvath, ACS Catal., 2014, 4, 1470–1477.
Science and Technological Fund of Anhui Province for 28 D. M. Alonso, S. G. Wettstein and J. A. Dumesic, Green Chem.,
́
Outstanding Youth (1508085J01) and the international tech-
nology cooperation plan of Anhui (No. 1503062030).
2013, 15, 584–595.
´
´
29 I. T. Horvath, H. Mehdi, V. Fabos, L. Boda and L. T. Mika,
Green Chem., 2008, 10, 238–242.
30 S. Hu, Z. Zhang, J. Song, Y. Zhou and B. Han, Green Chem.,
2009, 11, 1746–1749.
Notes and references
1 S. Dutta and S. Pal, Biomass Bioenergy, 2014, 62, 182–197.
2 F. Cherubini, Energy Convers. Manage., 2010, 51, 1412–1421.
31 Y. Shen, J. Sun, Y. Yi, M. Li, B. Wang, F. Xu and R. Sun,
Bioresour. Technol., 2014, 172, 457–460.
3 S. K. Maity, Renewable Sustainable Energy Rev., 2015, 43, 32 F. Salak Asghari and H. Yoshida, Ind. Eng. Chem. Res., 2006,
1446–1466. 45, 2163–2173.
4 R. J. Van Putten, J. C. van der Waal, E. D. De Jong, 33 M. Moreno-Recio, J. Santamarıa-Gonzalez and P. Maireles-
´
´
C. B. Rasrendra, H. J. Heeres and J. G. de Vries, Chem. Rev.,
2013, 113, 1499–1597.
Torres, Chem. Eng. J., 2016, 303, 22–30.
34 H. Xia, S. Xu and L. Yang, RSC Adv., 2017, 7, 1200–1205.
5 P. Zhou and Z. Zhang, Catal. Sci. Technol., 2016, 6, 3694– 35 Y. Yang, C. Hu and M. M. Abu-Omar, J. Mol. Catal. A: Chem.,
3712.
2013, 376, 98–102.
6 Z. Xue, M. G. Ma, Z. Li and T. Mu, RSC Adv., 2016, 6, 98874– 36 J. Wang, J. Ren, X. Liu, J. Xi, Q. Xia, Y. Zu and Y. Wang, Green
98892.
Chem., 2012, 14, 2506–2512.
7 A. Mukherjee, M. J. Dumont and V. Raghavan, Biomass 37 J. M. R. Gallo, R. Alamillo and J. A. Dumesic, J. Mol. Catal. A:
Bioenergy, 2015, 72, 143–183. Chem., 2016, 422, 13–17.
8 B. Saha and M. M. Abu-Omar, Green Chem., 2014, 16, 24–38. 38 X. Wu, J. Fu and X. Lu, Bioresour. Technol., 2012, 119, 48–54.
9 X. Tong, Y. Ma and Y. Li, Appl. Catal., A, 2010, 385, 1–13.
10 V. Choudhary, S. H. Mushrif, C. Ho, A. Anderko,
39 N. Shi, Q. Liu, Q. Zhang, T. Wang and L. Ma, Green Chem.,
2013, 15, 1967–1974.
V. Nikolakis, N. S. Marinkovic and D. G. Vlachos, J. Am. 40 M. Li, W. Li, Q. Liu, H. Jameel, H. M. Chang, S. An and L. Ma,
Chem. Soc., 2013, 135, 3997–4006.
BioResources, 2016, 11, 8239–8256.
11 Y. Zhang, J. Wang, X. Li, X. Liu, Y. Xia, B. Hu and Y. Wang, 41 Y. J. Pagan-Torres, T. Wang, J. M. R. Gallo, B. H. Shanks and
Fuel, 2015, 139, 301–307. J. A. Dumesic, ACS Catal., 2012, 2, 930–934.
12 B. F. Kuster and H. M Temmink, Carbohydr. Res., 1977, 54, 42 Y. Roman-Leshkov, M. Moliner, J. A. Labinger and
185–191. M. E. Davis, Angew. Chem., Int. Ed., 2010, 49, 8954–8957.
13 W. Mamo, Y. Chebude, C. Marquez-Alvarez, I. Dıaz and 43 G. Marcotullio and W. De Jong, Green Chem., 2010, 12, 1739–
E. Sastre, Catal. Sci. Technol., 2016, 6, 2766–2774. 1746.
14 T. S. Hansen, J. Mielby and A. Riisager, Green Chem., 2011, 44 S. K. Tyrlik, D. Szerszen, M. Olejnik and W. Danikiewicz, J.
13, 109–114.
Mol. Catal. A: Chem., 1996, 106, 223–233.
15 Y. Roman-Leshkov and J. A. Dumesic, Top. Catal., 2009, 52, 45 J. Tang, L. Zhu, X. Fu, J. Dai, X. Guo and C. Hu, ACS Catal.,
297–303. 2016, 7, 256–266.
16 Y. Roman-Leshkov, C. J. Barrett, Z. Y. Liu and J. A. Dumesic, 46 J. Li, Z. Jiang, L. Hu and C. Hu, ChemSusChem, 2014, 7, 2482–
Nature, 2007, 447, 982–985. 2488.
17 E. Combs, B. Cinlar, Y. Pagan-Torres, J. A. Dumesic and 47 Z. Jiang, J. Yi, J. Li, T. He and C. Hu, ChemSusChem, 2015, 8,
´
´
´
´
´
´
B. H. Shanks, Catal. Commun., 2013, 30, 1–4.
1901–1907.
14336 | RSC Adv., 2017, 7, 14330–14336
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