Synthetic Communications p. 597 - 609 (1991)
Update date:2022-08-11
Topics:
Zupan
Segatin
Crosslinked sulphonated polystyrene (Dowex 20 M) and various salts of crosslinked co-poly[styrene-4-vinylpyridine] with hydrogen halides were used as solid catalysts in investigations of the conversion of acids to esters. The role of the structure of the acid (acetic acid, benzoic acid), solvent (n-octane, toluene, n-butanol) and reaction temperature in the presence of polymer supported catalyst was tested in the reaction with n-butanol. Sulphonated crosslinked polystyrene (3a) was the most active catalys, similar activity was found with crosslinked co-poly[styrene-4-vinyl(pyridinium chloride)], while catalysts bearing a fluoride (3b) and iodide (3e) function were almost unreactive. The important role of co-solvents was also established.
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