Journal of Physical Chemistry p. 12415 - 12419 (1994)
Update date:2022-08-31
Topics:
Marconi, Dilma M. O.
Frescura, Vera L. A.
Zanette, Dino
Nome, Faruk
Bunton, Clifford A.
Hydrolyses of 2,4-dinitrophenyl acetate and octanoate (DNPA and DNPO, respectively) and benzoic anhydride (Bz2O) in the pH range 8.9-10.2 are inhibited by anionic micelles of sodium dodecyl sulfate (SDS), and reactions of fully micellar-bound substrates are very slow.The effect of micellized sodium dodecanoate, SDOD, depends on pH.At high pH reactions of DNPA and Bz2O involve OH- and are inhibited by SDOD, but there are significant rates at high
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