Journal of Physical Chemistry p. 5445 - 5446 (1993)
Update date:2022-08-11
Topics:
Graham, G. W.
Logan, A. D.
Shelef, M.
The rate of CO2 formation in each of the three reactant mixtures, CO + O2, CO + NO, and CO + O2 + NO, was measured over Pd(100) at partial pressures of 1 Torr and temperatures in the range 430 - 580 K.The rate in both CO + O2 and CO + NO followed the Arrhenius behaviour; in CO + NO, the rate was about 2 orders of magnitude lower than in CO + O2, whereas the apparent activation energy was about 30percent lower.The rate in CO + O2 + NO, however, was the same as in CO + O2 at temperatures above 480 K and was even greater at temperatures below 480 K.This behaviour may be contrasted with that in the case of Rh, where the addition of NO to CO + O2 drastically reduces the rate of CO2 formation.
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