Journal of the American Chemical Society p. 7061 - 7064 (2018)
Update date:2022-08-17
Topics:
Zeng, Rong
Feller, Moran
Diskin-Posner, Yael
Shimon, Linda J. W.
Ben-David, Yehoshoa
Milstein, David
Both CO and N2O are important, environmentally harmful industrial gases. The reaction of CO and N2O to produce CO2 and N2 has stimulated much research interest aimed at degradation of these two gases in a single step. Herein, we report an efficient CO oxidation by N2O catalyzed by a (PNN)Ru-H pincer complex under mild conditions, even with no added base. The reaction is proposed to proceed through a sequence of O-atom transfer (OAT) from N2O to the Ru-H bond to form a Ru-OH intermediate, followed by intramolecular OH attack on an adjacent CO ligand, forming CO2 and N2. Thus, the Ru-H bond of the catalyst plays a central role in facilitating the OAT from N2O to CO, providing an efficient and novel protocol for CO oxidation.
View MoreAnhui Gusheng Import&Export CO.,LTD
Contact:86-551-63662296
Address:Jinzhai Road NO.162 ,hefei, china
Angelisun(Chongqing) Pharmaceutical Co., LTD.
Contact:+86-23-68030926-816
Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Contact:+86-158-05817090
Address:ROOM 9F, FLAT 2, GUODU DEVELOPING BLDG, No.182, ZHAOHUI ROAD
Contact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Wuhan Hanye Chemical New Material Co.,Ltd
Contact:+86-27-85308141
Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Doi:10.1021/j150651a033
(1984)Doi:10.1055/s-1999-2977
(1999)Doi:10.1016/j.bioorg.2019.103025
(2019)Doi:10.1074/jbc.M117.790170
(2017)Doi:10.1002/chem.201704730
(2018)Doi:10.1017/S0266462300103228
()