Journal of Molecular Liquids p. 977 - 988 (2019)
Update date:2022-08-29
Topics:
Samsudin, Mohamad Fakhrul Ridhwan
Bacho, Nurfatien
Sufian, Suriati
Ng, Yun Hau
A series of carbon nanotubes (CNT) modified g-C3N4/BiVO4 photocatalysts were synthesized via wet-impregnation method and evaluated via degradation of phenol under solar light irradiation. The physicochemical properties of the as-developed photocatalyst were characterized using FTIR, XRD, FESEM, XPS, SAP and DR-UV Vis. The formation of g-C3N4/CNT/BiVO4 photocatalysts resulted in remarkable enhancement in the performance in which almost six times higher degradation rate in comparison to the pristine g-C3N4 and obeyed the pseudo-first-order kinetics and Temkin adsorption model. Congruously, the synergistic interaction between 2 wt% of CNT and 5 vol% of H2O2 as an oxidizing agent was capable of removing 80.6% of phenol within 120 min. The profound photodegradation performance monitored was attributed to the better crystallinity structure obtained as shown in XRD and XPS analysis. Furthermore, the intimate contact between the CNT, g-C3N4 and BiVO4 in the heterostructure sample as shown in FESEM micrograph images does help in allowing a smooth electron-hole pair separation and migration, resulting in more available ?OH and ?O2 ˉ radicals for photocatalytic degradation activities. The possible Z-scheme reaction mechanism has been proposed and active species trapping experiments have been carried out to find the role of active radical species responsible for the phenol degradation. Additionally, the g-C3N4/CNT/BiVO4 photocatalysts retained excellent stability even after several cycles. Congruently, a mathematical representation for understanding the interaction between CNT loading and H2O2 for photodegradation of phenol using response surface methodology (RSM) was successfully generated.
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