Combustion and sublimation calorimetric studies on acetylurea and trimethyl isocyanurate
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Source and publish data:
Journal of Chemical Thermodynamics p. 389 - 396 (1988)
Update date:2022-08-15
Topics:
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Authors:
Imamura, Akira
Murata, Shigeo
Sakiyama, Minoru
Article abstract of DOI:10.1016/0021-9614(88)90175-9
Standard enthalpies of formation in the crystalline and gaseous states have been determined for acetylurea and trimethyl isocyanurate by oxygen bomb-combustion calorimetry and sublimation calorimetry.Derived values are as follows:
.Stabilization energies related to intramolecular interaction between ?-electrons of carbonyl groups and lone-pair electrons of adjacent nitrogen atoms have been evaluated for acetamide and urea as well as for these compounds as enthalpy changes of "isodesmic" reactions using ethane as a reagent for the cleavage of CO-N bonds and are discussed.
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Full text of DOI:10.1016/0021-9614(88)90175-9
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