Journal of Organometallic Chemistry p. 105 - 112 (1983)
Update date:2022-08-25
Topics:
Tatsumi, T.
Hashimoto, K.
Tominaga, H.
Mizuta, Y.
Hata, K.
et al.
Double-bond migration of allylic alcohols and allylic alkyl ethers was catalytically effected with trans-Mo(N2)2(dpe)2(dpe=Ph2PCH2CH2PPh2).Decarbonylation occurred simultaneously in the case of allyl alcohol.Diallyl ether and allyl phenol ether gave the fragmentation products presumably through initial oxidative addition of the allyl-O bond.Allylamine was converted to N-propylideneallylamine and NH3.N,N-Dimethylallylamine was isomerized to N-trans-propenyldimethylamine, which was further transformed into 4-dimethylamino-1,3-hexadiene and dimethylamine on addition of oxygen.The catalytic allylation of methyl acetoacetate with allylic ethers and amines was achieved by use of trans-Mo(N2)2(dpe)2.
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