Electrochimica Acta p. 224 - 231 (2019)
Update date:2022-08-10
Topics:
Chen, Long
Wu, Honglun
Wang, Huiming
Chen, Liang
Pu, Xiangjun
Chen, Zhongxue
Vanadium-based compounds hold great promise as high capacity cathode candidate for future lithium rechargeable batteries. However, developing highly stable vanadium-based cathode materials with long cycle life remains a great challenge. Herein, we report a novel layered sodium vanadium oxide, NaVO3, as a promising cathode electrode contender. This material is capable of delivering a capacity of 224.8 mAh g?1 at the current density of 150 mA g?1, and a high rate capability of 85 mAh g?1 even at a high current density of 3 A g?1. Moreover, outstanding capacity retention of 77% after 1000 cycles is achieved. Ex situ characterizations verify that the excellent electrochemical performance of NaVO3 is attributed to superior structural stability and electrochemical reversibility upon long-term cycling. Furthermore, the lithium ion de/intercalation mechanism for NaVO3 is also revealed involving one electron transfer reaction between V5+ and V4+ redox couple. Considering the low cost and material sustainability as well as the outstanding electrochemical performances, we believe that NaVO3 is a highly promising cathode material for lithium rechargeable batteries and our findings may help to pave the way for developing vanadium-based layered structure materials for high-performance alkali and alkaline-earth ion batteries.
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