Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1031 - 1035 (1992)
Update date:2022-08-18
Topics:
Romakhin, A. S.
Budnikova, Yu. G.
Zaripov, I. M.
Kargin, Yu. M.
Nikitin, E. V.
et al.
An electrochemical method, based on the joint action of nucleophilic and electrophilic reagents on P4, is proposed in order to utilize white phosphorus in the formation of the esters of phosphorus acids.The action of alkoxide ions on white phosphorus in an alcohol medium in the presence of iodine generated at the anode leads to the formation of phosphate esters.A scheme in which the intermediate products are dialkyl and trialkyl phosphites and the side product is dialkyl alkylphosphonate is proposed for the process.Key words: Phosphate esters, white phosphorus, electrosynthesis.
View MoreContact:+86-519-86339586,13584329896
Address:Changzhou Scientific and Education Park
Contact:15973022782
Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Wuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Laohekou Jinghong Chemical Co.,Ltd
Contact:+86-0710-3702747
Address:163.East,Huagong Road,Laohekou
Doi:10.1039/c3nj00711a
(2013)Doi:10.1080/07328319808004719
(1998)Doi:10.1002/zaac.201000216
(2010)Doi:10.1021/acs.orglett.0c03241
(2020)Doi:10.1021/jo00893a013
(1975)Doi:10.1271/bbb.110303
(2011)