ACS Catalysis
Letter
Table 1. Enantioselective Cascade Reactions
solid state structure and reactivity will guide the design of future
generations of the catalyst based on the biaryl backbone, with a
goal of even more effective reactivity and increase stereo-
selectivity.
REFERENCES
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ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
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S
Data for enantioselective transformations with previously
described catalysts, experimental procedures, and com-
pound characterization data(PDF)
Structure of diacetone complex of Rh2(KC4P)2 33
Structure of diacetone complex of Rh2(R-KC4N)2 35
Structure of (1S,2R)-cyclopropanecarboxylate S27 (CIF)
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AUTHOR INFORMATION
Corresponding Author
ORCID
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(7) (a) Ahsan, M. Q.; Bernal, I.; Bear, J. L. Inorg. Chem. 1986, 25,
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M. P.; Westrum, L. J.; Wolthuis, W. N. E.; See, M. M.; Boone, W. P.;
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Author Contributions
‡(P.-A.C., K.S) These authors contributed equally.
Notes
The authors declare no competing financial interest.
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ACKNOWLEDGMENTS
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Dedicated to the memory of Prof. John Bear. We are grateful to
the Welch foundation (grant E-1744) and the NSF (grant
CHE-1352439) for financial support of this work. We are also
grateful to Huw Davies and co-workers for graciously providing
catalysts Rh2(S-BiTISP)2 (8c) and Rh2(S-BTPCP)4 for testing.
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