Tetrahedron Letters p. 2105 - 2108 (1989)
Update date:2022-08-16
Topics:
Torii, Sigeru
Dhimane, Anne-Lise
Araki, Yoshitaka
Inokuchi, Tsutomu
Biphenol electrosynthesis is achieved in a divided cell by a set of redox reactions from 2,6-di-tert-butylphenol (4) via the corresponding diphenoquinone 3.Phenol 4 can also lead to either the corresponding biphenol 2 or diphenoquinone 3 in a product-selective manner by electrooxidation in an undivided cell.The choice of solvent is a crucial factor for the product-selectivity.
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