Journal of Organic Chemistry p. 4634 - 4638 (1990)
Update date:2022-08-17
Topics:
Cunico, Robert F.
Kuan, Chia P.
Reduction of acetylsilane O-silylcyanohydrins gave β-amino-α-hydroxysilanes, which were diazotized to give α-silyl ketones.The addition of organolithium reagents to the cyanohydrins was accompanied by sequential C -> N and O -> N silyl group migrations.Silylation of the resulting lithium enolates afforded β-siloxy-N,N-bissilylenamines.
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