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RSC Advances
Journal Name
ARTICLE
Notes and references
DOI: 10.1039/C5RA11901D
Table 1: List of Zinc(II) based probes for the detection H2S available in literature
1. H. Kimura, Mol. Neurobiol., 2002, 26, 13-19.
2. R. Wang, Physiol.Rev., 2012, 92, 791-896.
Sensor Probe
LOD
Medium
Detectio
n
Reference
3. L. E. Rojo, J. A. Fernández, A. A. Maccioni, J. M. Jimenez and
R. B. Maccioni, Arch. Med. Res., 2008, 39, 1-16.
4. P. Kamoun, Med. Hypotheses, 2001, 57, 389-392.
5. G. Yang, L. Wu, S. Bryan, N. Khaper, S. Mani and R. Wang,
Cardiovasc Res., 2010, 86, 487-495.
time
8-aminoquinoline
based Zn-Complex
7-mercapto-4-
1.2
CH3CN-
Tris-HCl
Acetone-
HEPES
2 mins
M
1
M
ND
6. J. L. Wallace and R. Wang, Nat Rev Drug Discovery, 2015, 14
,
methylcoumarin
based Zn- Complex
4-Methyl-2, 6-
329-345.
7. V. S. Lin and C. J. Chang, Curr. Opin. Chem. Biol., 2012, 16
,
M
Ethanol-
Tris-HCl
ND
595-601.
Diformyl Phenol
based Zn- Complex
ARS-Zn(II)
level
8. M. Strianese, M. Staiano, G. Ruggiero, T. Labella, C.
Pellecchia and S. D'Auria, Methods Mol. Biol., 2012, 875
193-216.
9. C.-X. Duan and Y.-G. Liu, Curr. Med. Chem., 2013, 20, 2929-
2937.
,
92 nM
Methanol-
PBS
< 1 min
Present
work
LOD = Limit of Detection, ND=Not Determined
10. A. R. Lippert, J. Inorg. Biochem., 2014, 133, 136-142.
11. J. Li, C. Yin and F. Huo, RSC Adv., 2015, 5, 2191-2206.
Conclusions
In summary, we have reported Alizarin Red
12. N. Kumar, V. Bhalla and M. Kumar, Coord. Chem. Rev., 2013,
257, 2335-2347.
13. H. S. Jung, X. Chen, J. S. Kim and J. Yoon, Chem. Soc. Rev.,
2013, 42, 6019-6031.
S based
fluorescent sensing ensemble ARS-Zn(II) for the selective
detection of H2S in aqueous solution. The probe displayed
good selectivity and remarkable sensitivity. Compared to other
reported probes based on zinc complex for the detection of
H2S, we see that the present probe has number of advantage
as listed below. (a) Probe ARS-Zn(II) are commercially available
and very cheap, therefore this strategy eliminated the need of
multi-step synthesis, purification and characterization by
sophisticated analytical instrumentations, (b) longer excitation
14. K. Wang, H. Peng and B. Wang, J. Cell. Biochem., 2014, 115
,
1007-1022.
15. Z. Guo, G. Chen, G. Zeng, Z. Li, A. Chen, J. Wang and L. Jiang,
Analyst, 2015, 140, 1772-1786.
16. H. Peng, W. Chen, S. Burroughs and B. Wang, Curr. Org.
Chem., 2013, 17, 641-653.
17. D. A. Jose, M. Elstner and A. Schiller, Chem. - Eur. J., 2013,
19, 14451-14457.
18. X. Lou, D. Ou, Q. Li and Z. Li, Chem. Commun. 2012, 48, 8462-
8477.
(exc = 530 nm) and emission (em = 625nm) wavelengths are
more suitable for the biological purposes (c) fast response (<30
seconds) time with H2S (d) High detection limit (92 nM) (e)
Reversible ON-OFF-ON mode fluorescent change with H2S and
zinc makes ARS-Zn(II) as an recyclable probe for H2S (f)
Suitable for real time detection of H2S released from H2S
Donor molecule. In addition, fluorescent response with H2S is
also applied in live cell imaging. We anticipate that sensing
ensemble ARS-Zn(II) based fluorescent assays will be used in
future as powerful tool to monitor the release of H2S from
biological and pharmacological samples.
19. G. Ghale and W. M. Nau, Acc. Chem. Res., 2014, 47, 2150-
2159.
20. B. T. Nguyen and E. V. Anslyn, Coord. Chem. Rev., 2006, 250
,
3118-3127.
21. R. Villamil-Ramos and A. K. Yatsimirsky, Chem. Commun,
2011, 47, 2694-2696.
22. A. Nonaka, S. Horie, T. D. James and Y. Kubo, Org. Biomol.
Chem., 2008, 6, 3621-3625.
23. K. K. Ghosh, E. Yap, H. Kim, J.-S. Lee and Y.-T. Chang, Chem.
Commun., 2011, 47, 4001-4003.
24. W. M. J. Ma, M. P. Pereira Morais, F. D'Hooge, J. M. H. van
den Elsen, J. P. L. Cox, T. D. James and J. S. Fossey, Chem.
Commun., 2009, 532-534.
25. Y. Kubo, T. Ishida, A. Kobayashi and T. D. James, J. Mater.
Chem., 2005, 15, 2889-2895.
26. A. Safavi and M. Bagheri, Anal. Chim. Acta, 2005, 530, 55-60.
27. A. Abbaspour and L. Baramakeh, Sens. Actuators B: Chemical,
2006, 114, 950-956.
Acknowledgements
We acknowledge the Director and Head of the Chemistry
Department, NIT Kurukshetra, Haryana for the research
facilities. DAJ acknowledge the financial support of
Department of Science and Technology (DST) India for the
SERB-DST project grant SB/FT/CS-195/2013. AG thankful to the
financial support of DST, India for the SERB-DST young scientist
research project grants (SB/FT/CS-193/2013).
28. Z. Chen, Z. Wang, J. Chen and X. Chen, Biosens. Bioelectron.,
2012, 38, 202-208.
29. Z. Chen, Z. Wang, J. Chen and W. Gao, Talanta, 2012, 99
,
774-779.
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