Chemistry Letters p. 1841 - 1844 (1994)
Update date:2022-08-30
Topics:
Maki, Yuji
Satoh, Hikaru
Kurihara, Masayo
Endo, Takae
Watanabe, Gotaro
Ogura, Kyozo
Seven geranyl diphosphate analogues having oxygen atoms in their alkyl chains were synthesized and examined for their reactivities as substrates in the reaction catalyzed by pig liver farnesyl diphosphate synthase.All of these compounds acted as substrates to give farnesyl diphosphate analogues.It was suggested that the enzyme cavity for the geranyl moiety is tolerant enough to accommodate alkyl moietes containing oxygen atoms.
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