´
2025
M. Puszynska-Tuszkanow et al. / Polyhedron 30 (2011) 2016–2025
Table 6
The mode of ligand coordination in hydantoin derivatives in relation to metal hardness [50,51] and ionic radius [52].
Metal ion
Hardness (
g
)
Ionic radius (pm)
Donor atoms coordinated to the metal ions
References
1-Methylhydantoin
5,5-Diphenylhydantoin
5,5-Dimethylhydantoin
Soft
Au+
Ag+
5.4
6.9
7.7
8.0
137
115
102
86
N(3)
–
–
–
–
–
–
–
–
[11]
[14]
[13]
[12]
N(3), O(4)
N(3), O(4)
N(3), O(4)
Hg2+
Pt2+
Border line
Hard
Cu2+
Au3+
Ni2+
Zn2+
8.3
8.4
8.5
10.8
73
85
69
75
–
–
N(3)
–
N(3)
N(3)
–
N(3)
–
[53]
[54]
[34]
[55]
N(3) (this work)
–
–
K+
13.6
138
–
O(4)
–
[56]
´
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Acknowledgments
´
The authors are thankful to Ms. E. Mróz and Dr. A. Adach for
their help in recording of IR spectra and thermal decomposition
analysis, respectively. The helpful comments and language correc-
tion from Dr. W. Roth are greatly acknowledged. The author (MPT)
wishes to acknowledge the Polish Ministry of Higher Education
and Science for financial support (grant no. NN204 331037). Grant
from Wrocław University of Technology is also acknowledged.
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