3024
C.-Y. Sun et al. / Polyhedron 25 (2006) 3017–3024
Æ 0.25nCH OH (1), [Ni(o-CCA)(bpe)(H O)] Æ 0.5nH O (2),
[3] (a) S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem., Int.
Ed. 39 (2000) 2081;
3
2
n
2
[
M(p-CCA)(bpe)1.5(H O)] Æ nH O (M = Co, (3); Ni, (4)
2 n 2
(
b) M. Eddaoudi, J. Kim, N.L. Rosi, D.T. Vodak, J. Wachter, M.
O’Keeffe, O.M. Yaghi, Science 295 (2002) 469;
c) L. Pan, M.B. Sander, X.Y. Huang, J. Li, M. Smith, E. Bittner, B.
and [Co(o-BDC)(bpe)(H O)] Æ nH O (5)). In complex 1,
2
n
2
bpe ligands link Co(II) ions into wave-like chains, while
in complex 3, Co(II) ions are bridged by bpe into brick-
wall-like grids, which is mainly attributed to coordination
characteristics of o-CCA anion and p-CCA anion, respec-
tively. The position of functional dicarboxylate groups
takes an important role in the architectures of metal-
organic frameworks. Complexes 1–4 all possess 3D compli-
cated and different metal-organic frameworks, while
complex 5 is of (4,4) 2D grid-like layers with cavities. These
results show that in order to construct regular geometry, it
is feasible to use mixed rigid and flexible ligands rather
than mixed flexible ligands.
(
Bochrath, J.K. Johnson, J. Am. Chem. Soc. 126 (2004) 1308.
[4] (a) M. Albrecht, M. Lutz, A.L. Spek, G. Koten, Nature 406 (2000)
9
70;
(
(
b) L.G. Beauvais, M.P. Shores, J.R. Long, J. Am. Chem. Soc. 122
2000) 2763.
[
5] (a) M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M.
O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34 (2001) 319;
(b) M.E. Braun, C.D. Steffek, J. Kim, P.G. Rasmussen, O.M. Yaghi,
Chem. Commun. (2001) 2532;
(
c) C. Ruiz-P e´ rez, P. Lorenzo-Luis, M. Hern a´ ndez-Molina, M.M. Laz,
F.S. Delgado, P. Gili, M. Julve, Eur. J. Inorg. Chem. (2004) 3873.
6] (a) B.Q. Ma, P. Coppens, Chem. Commun. (2003) 2290;
(b) E. Coronado, J.R. Gal a´ n-Mascar o´ s, C.J. G o´ mez-Garc ´ı a, E.
Mart ´ı nez-Ferrero, S.V. Smaalen, Inorg. Chem. 43 (2004) 4808.
7] (a) M. Oh, G.B. Carpenter, D.A. Sweigart, Angew. Chem., Int. Ed.
[
[
5
. Supplementary data
4
2 (2003) 2025;
b) F.A.A. Paz, J. Klinowski, Inorg. Chem. 43 (2004) 3882.
[8] (a) J.F. Ma, J. Yang, G.L. Zheng, L. Li, J.F. Liu, Inorg. Chem. 42
(
Crystallographic data for the structural analysis have
(
(
(
2003) 7531;
been deposited with the Cambridge Crystallographic Data
Centre, CCDC Nos. 601065–601069 for 1–5, respectively.
Copies of this information may be obtained free of charge
from the CCDC, 12 Union Road, Cambridge CB2 1EZ,
b) D.N. Dybtsev, H. Chun, K. Kim, Angew. Chem., Int. Ed. 43
2004) 5033.
[
9] M.C. Hong, W.P. Su, R. Cao, M. Fujita, J.X. Lu, Chem. Eur. J. 6
(
[10] H. Kumagai, Y. Oka, K. Inoue, M. Kurmoo, J. Chem. Soc., Dalton
Trans. (2002) 3442.
2000) 427.
[
11] F. Li, Z. Ma, Y.L. Wang, R. Cao, W.H. Bi, X. Li, CrystEngComm. 7
2005) 569.
12] (a) H.L. Li, M. Eddaoudi, M. Okeeffe, O.M. Yaghi, Nature 402
1999) 276;
(
Acknowledgements
´
[
(
´
This project is supported by National Nature Science
Foundation of China (20331010, 20501003).
(b) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. Okeeffe,
O.M. Yaghi, Science 295 (2002) 469;
(
c) K. Barthelet, J. Marrot, D. Riow, G. F e´ rey, Angew. Chem., Int.
Ed. 41 (2002) 281;
References
(
(
d) S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem., Int. Ed. 43
2004) 2334.
[
1] (a) M. Fujita, Y.J. Kwon, S. Washizu, K. Ogura, J. Am. Chem. Soc.
16 (1994) 1151;
[13] Z.Y. Fu, X.T. Wu, J.C. Dai, S.M. Hu, W.X. Du, H.H. Zhang, R.Q.
Sun, Eur. J. Inorg. Chem. (2002) 2730.
1
(
(
b) T. Sawaki, Y. Aoyama, J. Am. Chem. Soc. 121 (1999) 4793;
c) J.S. Seo, D. Whang, H. Lee, S.I. Jun, J. Oh, Y. Jeon, K. Kim,
[14] G.M. Sheldrick, SHELXTL 97, Program for the Refinement of Crystal
Structures, University of G o¨ ttingen, Germany, 1997.
[15] Z.Y. Fu, S.M. Hu, J.C. Dai, J.J. Zhang, X.T. Wu, Eur. J. Inorg.
Chem. (2003) 2670.
Nature 404 (2000) 982;
d) L. Pan, H.M. Liu, X.G. Lei, X.Y. Huang, D.H. Olson, N.J.
(
Turro, J. Li, Angew. Chem., Int. Ed. 42 (2003) 542.
2] (a) K.S. Min, M.P. Suh, Chem. Eur. J. 7 (2001) 303;
[16] J. Luo, M. Hong, R. Wang, R. Cao, L. Han, Z. Lin, Eur. J. Inorg.
Chem. (2003) 2705.
[
(
b) K. Uemura, S. Kitagawa, M. Kondo, K. Fukui, R. Kitaura, H.C.
Chang, T. Mizutani, Chem. Eur. J. 8 (2002) 3587;
c) D.N. Dybtsev, H. Chun, S.H. Yoon, D. Kim, K. Kim, J. Am.
Chem. Soc. 126 (2004) 32.
[17] X.Q. Lu, J.J. Jiang, C.L. Chen, B.S. Kang, C.Y. Su, Inorg. Chem. 44
(2005) 4515.
[18] C.Y. Sun, X.J. Zheng, S. Gao, L.C. Li, L.P. Jin, Eur. J. Inorg. Chem.
(2005) 4150.
(