Journal of Chemical Thermodynamics p. 1075 - 1096 (1990)
Update date:2022-08-17
Topics:
Chirico, R. D.
Gammon, B. E.
Knipmeyer, S. E.
Nguyen, A.
Strube, M. M.
et al.
Measurements leading to the calculation of the ideal-gas thermodynamic properties for dibenzofuran are reported.Experimental methods included combustion calorimetry, adiabatic heat-capacity calorimetry, comparative, ebulliometry, inclined-piston manometry, and differential scanning calorimetry.Entropies, enthalpies, and Gibbs energies of formation were derived for the ideal gas for selected temperatures between 298.15 K and 720 K.The critical temperature and critical density were determined with a differential scanning calorimeter, and the critical pressure was derived.These are the first reported experimental critical properties for dibenzofuran.Measured combustion enthalpies, vapour pressures, critical properties, and ideal-gas entropies are compared with literature values.
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