Chemistry Letters p. 245 - 246 (1997)
Update date:2022-08-10
Topics:
Hatakeda, Kiyotaka
Ikushima, Yutaka
Ito, Shota
Saito, Norio
Sato, Osamu
The supercritical water oxidation (SCWO) of a PCB of 3-chlorobiphenyl (1) was carried out at a temperature of 673 K and a pressure of 30 MPa with a flow reactor. The initial concentrations of (1) and hydrogen peroxide ranged from 1.84 X 10 -3 to 8.74 X 10 -2 M (1 M=1 mol dm -3), and 0.181 to 2.67 M, respectively. The decomposition of (1) was higher than 99.9% so long as hydrogen peroxide was stoichiometrically added.
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