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ChemComm
DOI: 10.1039/C6CC08505A
COMMUNICATION
Journal Name
higher than that for styrene hydrogenation when their mixture
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(styrene:nitrobenzene = 1:1) was used as the substrate.
In summary, a low-cost, easily available, and highly active and
chemoselective nickel catalyst was developed for the
hydrogenation of substituted nitroarenes to the corresponding
anilines, as well as for the hydrogenation of α,β-unsaturated
nitroarenes to oximes. The oxygen surface groups on the
carbon support were found to play a key role in both
stabilizing Ni particles and preferential adsorption of nitro
group, as a consequence, leading to the high activity and
chemoselectivity. The strategy presented here is expected to
find applications in chemoselective hydrogenation of other
multifunctional substrates.
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We are grateful to the supports from the National Natural
Science Foundation of China (21373206, 21522608 and
Schunemann, A. Bruckner and M. Beller, Science, 2013, 342
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21673228), the Strategic Priority Research Program of the
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,
Chinese Academy of Sciences (XDB17020100), and the
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