Journal of Physical Chemistry p. 5010 - 5014 (1982)
Update date:2022-08-11
Topics:
Bunton, Clifford A.
Buzzaccarini, Francesco de
The reaction of p-bromophenacylmethyl picryl ether with bromide ion was followed in a microemulsion of cetyltrimethylammonium bromide (CTABr), n-octane, and n-butyl or tert-amyl alcohol.The second-order rate constants in the microemulsion droplets were estimated from the concentration of Br- in the droplets determined electrochemically.These rate constants are insensitive to the composition of the microemulsion, are similar to those in CTABr micelles in water and in aqueous n-butyl, n-hexyl, and tert-amyl alcohol, and are slightly higher than those estimated for the reaction in water.They are smaller than rate constants in the water-alcohol mixtures of relatively low water content.
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