Please do not adjust margins
Journal of Materials Chemistry C
Page 8 of 10
DOI: 10.1039/C6TC03239G
ARTICLE
Journal Name
T. Hori, M. C. Yoon, N. Aratani, A. Osuka, D. Kim and M. R.
Wasielewski, J. Am. Chem. Soc., 2010, 132, 1383-1388.
13 (a) H. Mori, T. Tanaka, S. Lee, J. M. Lim, D. Kim and A. Osuka,
J. Am. Chem. Soc., 2015, 137, 2097-2106; (b) T. Tanaka, N.
Aratani, J. M. Lim, K. S. Kim, D. Kim and A. Osuka, Chem. Sci.,
2011, 2, 1414-1418; (c) A. Tsuda, Y. Nakamura and A. Osuka,
Chem. Commun., 2003, 1096-1097.
14 (a) E. G. A. Notaras, M. Fazekas, J. J. Doyle, W. J. Blau and M.
O. Senge, Chem. Commun., 2007, 2166-2168; (b) M.
Zawadzka, J. Wang, W. J. Blau and M. O. Senge, J. Phys.
Chem. A, 2013, 117, 15-26.
(negative lensing effect) which is characterized by pre-focal
maxima followed by post focal minima. The refractive
nonlinearity measured is of electronic origin and not of
thermal origin. The large third-order nonlinearities were
attributed to the electron delocalization in the 22π-electron
molecular frameworks of these porphyrins. Fs pump
supercontinuum probe transient absorption experiments
revealed excited state absorptions in two wavelength regions,
namely 450 to 570 nm and 620 to 750 nm. The wavelength
region 570 nm to 620 nm represented ground state bleaching.
This report constitutes a desolate study where nonlinear
absorption, refraction as well as TPA are reported for
tetraoxa[22]porphyrin(2.1.2.1)s.
15 (a) K. Singh, T. S. Virk, J. Zhang, W. Xu and D. Zhu, Chem.
Commun., 2012, 48, 121-123; (b) K. Singh, T. S. Virk, J. Zhang,
W. Xu and D. Zhu, Chem. Commun., 2012, 48, 12174-12176.
16 K. Singh, S. Arora, K. Makhal, P. Kaur and D. Goswami, RSC
Adv., 2016,
17 M. J. Frisch, et al. Gaussian 09, Revision A.02, Gaussian, Inc.,
Wallingford CT, 2009(for complete reference see ESI ).
6, 22659-22663.
†
18 D. G. Kong, Q. Chang,H. A. Ye, Y. C. Gao, Y. X. Wang, X. R.
Zhang, K. Yang, W. Z. Wu and Y. L. Song, J. Phys. B, At. Mol.
Opt. Phys.,2009, 42, 065401.
19 X. Q. Yan, Z. B. Liu, S. Shi, W. Y. Zhou and J. G. Tian, Opt.
Express, 2010, 18, 26169-26174.
20 Z. Chen, C. S. Wannere, C. Corminboeuf, R. Puchta and P. von
R. Schleyer, Chem. Rev., 2005, 105, 3842-3888.
21 Z. S. Yoon, J. H. Kwon, M. C. Yoon, M. K. Koh, S. B. Noh, J. L.
Sessler, J. T. Lee, D. Seidel, A. Aguilar, S. Shimizu, M. Suzuki,
A. Osuka and D. Kim, J. Am. Chem. Soc., 2006, 128, 14128-
14134.
5 Acknowledgements
The work was supported by SERB (DST) funding (project
SB/S1/OC-45/2013) to KS. SA and KM thank UGC for research
fellowships. DG thanks ISRO and MHRD for funding. We all
thank GNDU Amritsar and IIT Kanpur for facilities and DST FIST
for utilizing amplified laser system and for TA.
6 Notes and references
22 M. C. Yoon, S. Cho, M. Suzuki, A. Osuka and D. Kim, J. Am.
Chem. Soc., 2009, 131, 7360-7367.
23 R. G. Pearson, Chemical Hardnesss Applications from
Molecules to Solids; VCH-Wiley: Weinheim, Germany, 1997.
24 R. L. Sutherland, Handbook of Nonlinear Optics (Marcel
Dekker, New York, 2003).
25 F. P. Schafer, Dye Lasers, Springer Verlag, 1990
26 W. Feng, W. Yi, H. Wu, M. Ozaki and K. Yoshino, J. Appl.
Phys., 2005, 98, 034301.
1
J. Schmitt, V. Heitz, A. Sour, F. Bolze, H. Ftouni, J. F. Nicoud,
,
L. Flamigni and B. Ventura, Angew Chem. Int. Ed., 2015, 54
169-173.
(a) A. Bessette and G. S. Hanan, Chem. Soc. Rev., 2014, 43
2
,
3342-3405; (b) J. S. Lindsey and D. F. Bocian, Acc. Chem. Res.,
2011, 44, 8, 638-650; (c) H. Dong, H. Zhu, Q. Meng, X. Gong
and W. Hu, Chem. Soc. Rev., 2012, 41, 1754-1808.
3
(a) T. Chen, Z. Sun, S. Zhao, C. Ji and J. Luo, J. Mater. Chem. C,
2016, 4, 266-271; (b) H. S. Nalwa and S. Miyata, Nonlinear
27 O. V. Przhonska, J. H. Lim, D. J. Hagan, E. W. Van Stryland, M.
,
V. Bondar, and Y. L. Slominsky, J. Opt. Soc. Am. B, 1998, 15
802-809.
Optics of Organic Molecules and Polymers, eds CRC Press,
Boca Raton, FL, 1997.
S. Singh, A. Aggarwal, N. V. S. Dinesh, K. Bhupathiraju, G.
Arianna, K. Tiwari and C. M. Drain, Chem. Rev., 2015, 115
10261-10306.
K. J. McEwan, P. A. Fleitz, J. E. Rogers, J. E. Slagle, D. G.
McLean, H. Akdas, M. Katterle, I. M. Blake and H. L.
Anderson, Adv. Mater., 2004, 16, 21, 1933-1935.
28 T. H. Wei, D. J. Hagan, M. J. Sence, E. W. van Stryland, J. W.
Perry, and D. R. Coulter, App. Phys. B, 1992, 54, 46-51.
29 S. V. Rao, D. N. Rao, J. A. Akkara, B.S, DeCrristofano,
D.V.G.L.N. Rao, Chem. Phys. Lett. 1998, 297, 491-498.
30 G. S. He, C. Weder, P. Smith and P. N. Prasad,IEEE Journal of
Quant. Electron.,1998, 34, 2279-2285.
31 S. L. Guo, X. Li, H. T. Wang, X. Z. You, N. B. Ming, Optik, 2003,
114, 58-62.
32 A. Auger, W. J. Blau, P. M. Burnham, I. Chambrier, M. J. Cook,
B. Isare, F. Nekelson and S. M. O’Flaherty, J. Mater. Chem,
2003,13, 1042-1047.
4
5
,
6
7
8
9
S. M. O’Flaherty, S. V. Hold, M. J. Cook, T. Torres, Y. Chen, M.
Hanack and W. J. Blau, Adv. Mater., 2003, 15, 19-32.
M. Sheik-bahae, A. A. Said, E. W. Van Stryland, Opt. Lett.
1989, 14, 955-957.
M. Sheik-bahae, A. A. Said, T. –H. Wei, D. J. Hagan and E. W.
V. Stryland, IEEE J. Quantum Electron. 1990, 26, 760-769.
P. B. Chapple, J. Staromlynska, J. A. Hermann, T. J. Mckay and
33 M. Lin, H. P. Li, S. H. Tang and W. Ji, Appl. Phys. B.,2000, 70
587-591.
,
34 X. Liu, S. Guo, H. Wang and L. Hou, Opt. Commun.,2001, 197
431-437.
,
R. G. Mcduff, J. Nonlinear Opt. Phys. Mater. 1997, 6, 251-
293.
10 (a) T. K. Chandrashekar and S. Venkatraman, Acc. Chem. Res.,
2003, 36, 676–691; (b) J. M. Lim, K. Ganesan, Y. M. Sung, A.
Srinivasan, T. K. Chandrashekar and D. Kim, Chem. Commun.,
2014, 50, 4358-4360.
11 Z. S. Yoon, J. Yang, H. Yoo, S. Cho and D. Kim, Photophysical
properties of various directly linked porphyrin arrays, in
Handbook of Porphyrin Science with Applications to
Chemistry, Physics, Materials Science, Engineering Biology
and Medicine, ed. K. M. Kadish, K. M. Smith and R. Guilard,
World Scientific Publishers, Singapore, 2010, vol. 1.
12 (a) S. Cho, M. C. Yoon, K. S. Kim, P. Kim and D. Kim, Phys.
Chem. Chem. Phys., 2011, 13, 16175-16181; (b) T. M. Wilson,
35 G. Sreekumar, P. G. Louie Frobel, C. I. Muneera, K.
Sathiyamoorthy, C. Vijayan and C. Mukherjee, J. Opt. A. :
Pure Appl. Opt., 2009,11, 125204.
36 J. S. Shirk, R.G. S. Pong, S. R. Flom, H. Heckmann and M.
Hanack, J. Phys. Chem. A, 2000, 104, 1438-1449.
37 D. N. Christodoulides, I. C. Khoo, G. J. Salamo, G. I. Stegeman
and Eric W. Van Stryland, Advances in Optics and Photonics,
2010, 2, 60-200.
38 M. Konstantaki, E. Koudoumas, S. Couris, P. Laine, E.
Amouyal and S. Leach, J. Phys. Chem. B, 2001, 105, 10797-
10804.
8 | J. Name., 2012, 00, 1-3
This journal is © The Royal Society of Chemistry 20xx
Please do not adjust margins