Tetrahedron p. 2937 - 2940 (1999)
Update date:2022-08-17
Topics:
Doerner, Thomas
Gleiter, Rolf
Neugebauer, Franz A.
Radical anions of acyclic vicinal oligoketones with up to five CO units, 1a-d(·-) and 2a-c(·-), were generated by reduction of the parent compounds with potassium in presence of kryptofix 222 and studied by ESR measurements. The inverse correlation between g-values and the amount of spin populations on the terminal substituents prove that these radical anions are extended π-systems.
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