Bulletin of the Chemical Society of Japan p. 3611 - 3612 (1981)
Update date:2022-08-11
Topics:
Suga, Sohei
Segi, Masahito
Kitano, Kiyoyuki
Masuda, Shinji
Nakajima, Tadashi
The alkylation of benzene with (+)-2-chlorobutane (1) by Lewis acid catalyst gave stereospecifically (-)-2-phenylbutane (2) with inversion of configuration at low temperature for short reaction time.A lowering of the stereospecificity of the reaction was found to be partly due to the racemization of (+)-1- and (-)-2.
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