Turkish Journal of Chemistry p. 1622 - 1633 (2019)
Update date:2022-08-16
Topics:
Ya?ar, Sedat
Akko?, Mitat
?zdemir, Nam?k
?zdemir, ?smail
The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC: N -heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr 3 ] ? [NHC] + . The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki–Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.
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