Synthetic Communications p. 1557 - 1564 (1994)
Update date:2022-08-11
Topics:
Johnson
Donohoe
Kang
Allylmagnesium bromide has been shown to cross-couple with α,ω- dihaloalkanes in the presence of dilithium tetrachlorocuprate to yield, depending on reaction conditions, mono-coupled haloalkenes or di-coupled alkadienes. The order of the reactivity of the dihalides is I > Br >> CI and secondary halides show greater reactivity than primary halides.
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