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[12] A mechanism that proceeds via a palladacyclobutenone inter-
mediate is possible and cannot be ruled out at this time.
[13] No reaction occurred with internal alkynes.
[14] For [3+2] annulation between cyclopropenones and internal al-
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[15] No reaction was observed when 3aj was simply heated at
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[17] We thank two referees for their valuable comments and sugges-
tions on the mechanism.
Received: February 10, 2013
Published Online: May 23, 2013
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Krebs, Angew. Chem. 1965, 77, 10–22; Angew. Chem. Int. Ed.
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