Phosphorus, Sulfur and Silicon and the Related Elements p. 64 - 68 (2017)
Update date:2022-08-16
Topics:
Demchuk, Oleg M.
?wierczyńska, Wioletta
Dziuba, Kamil
Frynas, S?awomir
Flis, Anna
Pietrusiewicz, K. Micha?
A variety of tertiary phosphine sulfides have been reduced by Raney-Ni to give the corresponding phosphineswith high efficiency and undermild conditions. Alkyl, aryl, acyclic, cyclic, aswell as sterically crowded phosphine sulfides are reduced with equal facility. Optically active P-stereogenic phosphine sulfides are reduced stereospecifically with clean retention of configuration at P. Reductions of unsaturated phosphinesulfides is not fully chemoselective and takes place with concomitant partial reduction of the double bond. Clean reduction of the unsaturated phosphine sulfides to the corresponding fully saturated phosphines can be achieved in one step by running the reduction under H2atmosphere (balloon).
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