Journal of Inorganic and General Chemistry
ARTICLE
Zeitschrift für anorganische und allgemeine Chemie
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Synthesis of Triaminoguanidinium Dinitramide (4): Silver dinitr-
amide (0.21 g, 1.0 mmol) and triaminoguanidinium chloride (0.14 g,
1.0 mmol) were dissolved in distilled water (5 mL), respectively. The
two solutions were mixed and stirred for 0.5 h to precipitate the silver
chloride. The precipitate was filtered off under reduced pressure. The
filtrate was evaporated to dryness to afford yellow crystal triaminogu-
anidinium dinitramide 0.20 g, with a yield of 96%. M.p. 80°C. IR
(KBr): ν˜ 3400, 1702, 1640, 1530, 1384, 1186 cm–1. UV/Vis (H2O):
1
λmax/nm: 284, 235. H NMR (600 MHz, (CD3)2CO, 25°C): δ = 8.57,
4.45 ppm. 13C NMR (400 MHz, (CD3)2CO, 25°C): δ = 159.6 ppm:
Synthesis of N,NЈ,NЈЈ-Tri(propan-2-ylidene)methanetriamium Di-
nitramide (NTAGDN) (5): The crude triaminoguanidinium dinitram-
ide (21 mg, 0.1 mmol) was dissolved in acetone (5 mL) and stirred for
30 min. After filtration, the acetone solution was vaporized slowly in
room temperature to yield light yellow crystals 15 mg, with a yield of
72%. C10H21N9O4: calcd. C 36.25; H 6.34; N 38.07%; found C 36.19;
H 6.37; N 38.05%. IR (KBr): ν˜ 3407, 3259, 3184, 2956, 1675, 1634,
1528, 1434, 1384, 1186, 1102, 1005, 759, 572 cm–1. UV/Vis (H2O):
1
λmax/nm: 285, 244. H NMR (600 MHz, (CD3)2CO, 25°C): δ = 9.86
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(s, 3 H, NH), 2.96 (s, 18 H, CH3) ppm. 13C NMR (150 MHz,
(CD3)2CO, 25°C): δ = 161.59 [C(CH3)], 149.83 [CN(NH)2], 24.42 and
16.69 [C(CH3)2]. 15N NMR: δ = 323.13 [NH], 283.21[N(NO2)2],
272.79 [NC(CH3)2], 126.75 and 129.65 [NO2] ppm.
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Crystallographic data (excluding structure factors) for the structure in
this paper have been deposited with the Cambridge Crystallographic
Data Centre, CCDC, 12 Union Road, Cambridge CB21EZ, UK. Copies
of the data can be obtained free of charge on quoting the depository
number CCDC-1402693 (5) (Fax: +44-1223-336-033; E-Mail:
deposit@ccdc.cam.ac.uk, http://www.ccdc.cam.ac.uk)
197, 199–203.
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Acknowledgements
We are grateful for financial support from the National Natural Science
Foundation of China (Project No. 21301142, 51372211), National De-
fense Fundamental Research Projects (Project No. A3120133002),
Youth Innovation Research Team of Sichuan for Carbon Nanomaterials
(2011JTD0017), Applied Basic Research Program of Sichuan Province
(2014JY0170) and Southwest University of Science and Technology
Researching Project (13zx9107).
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Received: August 9, 2015
Published Online: October 14, 2015
Z. Anorg. Allg. Chem. 2015, 2630–2636
2636
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim