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alyzed oxidative vicinal diazidation of alkenes, in which
TMSN3 was used as the azide source and NFSI was
used as oixdant. Both styrenes and unactivate alkenes
could be transferred to corresponding vicinal diazides
with this method. And trans diazides were obtained as
major products from cyclic alkenes with moderate to
good diastereoselectivities. This reaction afforded an
efficient way for the synthesis of useful 1,2-diamines
after hydrogenation. Further mechanism study and im-
provement on the stereoselectivity are in progress.
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Acknowledgement
We are grateful for financial support from the Na-
tional Basic Research Program of China (No.
973-2015CB856600), and the National Natural Science
Foundation of China (Nos. 21225210, 21421091 and
21532009).
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