Phosphorus, Sulfur and Silicon and the Related Elements p. 520 - 527 (2015)
Update date:2022-08-11
Topics:
Aghapour, Ghasem
Mohamadian, Samaneh
A mild and one-pot conversion of benzylic alcohols to their corresponding gem-dichlorides is reported for the first time using chlorodiphenylphosphine (ClPPh2) and 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) in dichloromethane under neutral conditions and at room temperature. The present method can be efficiently used for preparation of gem-dichlorides even in the presence of some other functional groups with excellent chemoselectivity.
View Morewebsite:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
Hangzhou innopharma technology Co,.Ltd.
Contact:+86-13388601988
Address:Room845,lixin building, moganshan road, hangzhou, china
Contact:0086-22-23410962
Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Contact:+86-15850770348
Address:51 OF XIANGFANGCUN ROAD, Nanjing 210002, China
JIANGXI AIFEIMU TECHNOLOGY CO.,LTD
Contact:+86-570-6040289
Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP
Doi:10.1039/c9dt04485j
(2020)Doi:10.1016/S0040-4039(01)91262-6
(1984)Doi:10.1002/anie.200704972
(2008)Doi:10.1021/jm0494873
(2004)Doi:10.1080/09168451.2019.1576501
(2019)Doi:10.1055/s-1998-1574
(1998)