Journal of Physical Chemistry p. 3024 - 3028 (1980)
Update date:2022-08-11
Topics:
Dorer, F. H.
Salomon, K. E.
On direct photolysis or Hg(3P1) sensitized decomposition trimethylene sulfoxide (I) undergoes fragmentation in the gas phase to yield ethylene, propylene, and cyclopropane.There is a nonrandom distribution of the available energy in the cyclopropane-forming reaction which is interpreted to indicate that, in order to conserve spin angular momentum, this reaction channel may be driven to produce SO(1Δ) during direct photolysis, and SO(3Σ) during Hg(3P1) sensitized decomposition.There is a comparison of some aspects of the photochemistry of trimethylene sulfoxide to cyclobutanone photochemistry.
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