Tetrahedron Letters p. 2303 - 2306 (1999)
Update date:2022-08-25
Topics:
Riahi, Abdelkhalek
Henin, Francoise
Muzart, Jacques
The chromium oxide-catalyzed oxidation of allylic alcohols - R1CH(OH)CR2=CHR3 - by ROOH (R= t-Bu, PhCMe2) affords generally a mixture of R1COCR2=CHR3 and R1CH=CR2COR3. The rate of the reaction and the ratio between the two oxidized compounds both depend on the nature of R. It has been concluded that the oxidative species and the reactive intermediates contain this R group.
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