Paper
RSC Advances
for the superior catalytic performance of PtSn/SiO
2
-MTSG
L ´o pez, M. C. Barrera, J. Escobar, J. Navarrete and
catalyst. Meanwhile, a parallel reaction paths model was
I. Hern ´a ndez, Appl. Catal., B, 2011, 106, 14–25.
proposed for the hydrogenation of AcOH based on the kinetic 21 L. Jiao and J. R. Regalbuto, J. Catal., 2008, 260, 329–341.
parameter analysis, in which ethanol and AcOEt were formed 22 M. Schreier and J. R. Regalbuto, J. Catal., 2004, 225, 190–202.
competitively through the adsorbed ethoxy, derived from the 23 J. T. Miller, M. Schreier, A. J. Kropf and J. R. Regalbuto, J.
dissociated adsorption of AcOH.
Catal., 2004, 225, 203–212.
2
2
4 C. A. Emeis, J. Catal., 1993, 141, 347–354.
5 D. F. Cox, G. B. Hound and H. A. Laitinen, Langmuir, 1985,
Acknowledgements
1
, 269–273.
2
2
2
6 N. Kamiuchi, K. Taguchi, T. Matsui, R. Kikuchi and
K. Eguchi, Appl. Catal., B, 2009, 89, 65–72.
7 Y. G. Kolyagin, V. Ordomsky, Y. Khimyak, A. Rebrov,
F. Fajula and I. Ivanova, J. Catal., 2006, 238, 122–133.
8 A. Goguet, M. Aouine, F. J. Cadete Santos Aires, A. De
Mallmann, D. Schweich and J. P. Candy, J. Catal., 2002,
We are grateful to the nancial support from the National
Nature Science Foundation of China (21276186, 21325626,
9
1434127, U1510203) and the Tianjin Natural Science Founda-
tion (13JCZDJC33000). We also thank professor Shishan Sheng
Dalian Institute of Chemical Physics, Chinese Academy of
(
Sciences) for his constructive advances in the XPS results.
2
09, 135–144.
9 A. Goguet, D. Schweich and J. P. Candy, J. Catal., 2003, 220,
80–290.
2
3
2
References
0 L. Shi, G. M. Deng, W. C. Li, S. Miao, Q. N. Wang,
1
2
3
4
R. Pestman, R. M. Koster, E. Boellaard, A. M. van der Kraan
and V. Ponec, J. Catal., 1998, 174, 142–152.
R. Pestman, R. M. Koster, J. A. Z. Pieterse and V. Ponec, J.
Catal., 1997, 168, 255–264.
R. Pestman, A. van Duijne, J. A. Z. Pieterse and V. Ponec, J.
Mol. Catal. A: Chem., 1995, 103, 175–180.
H. G. Manyar, C. Paun, R. Pilus, D. W. Rooney,
J. M. Thompson and C. Hardacre, Chem. Commun., 2010,
W. P. Zhang and A. H. Lu, Angew. Chem., Int. Ed., 2015, 54,
1
–6.
1 C. Yu, H. Xu, Q. Ge and W. Li, J. Mol. Catal. A: Chem., 2007,
66, 80–87.
3
3
3
2
2 F. Jiang, L. Zeng, S. Li, G. Liu, S. Wang and J. Gong, ACS
Catal., 2015, 5, 438–447.
3 A. Suknev, V. Zaikovskii, V. Kaichev, E. Paukshtis,
E. Sadovskaya and B. Bal'zhinimaev, J. Energy Chem., 2015,
46, 6279–6281.
24, 646–654.
5
6
7
8
9
J. Goldemberg, Science, 2007, 315, 808–810.
J. Goldemberg, Science, 2007, 317, 1325.
W. Rachmady and M. A. Vannice, J. Catal., 2002, 209, 87–98.
W. Rachmady and M. A. Vannice, J. Catal., 2002, 207, 317–330.
V. Pallassana and M. Neurock, J. Catal., 2002, 209, 289–305.
3
3
4 L. Chen, Y. Li, X. Zhang, Q. Zhang, T. Wang and L. Ma, Appl.
Catal., A, 2014, 478, 117–128.
5 G. Neri, G. Rizzo, C. Crisafulli, L. De Luca, A. Donato,
M. Musolino and R. Pietropaolo, Appl. Catal., A, 2007, 325,
15–24.
1
1
1
1
1
1
1
1
1
1
2
0 K. Zhang, H. Zhang, H. Ma, W. Ying and D. Fang, Asian J.
3
3
6 H. Zhan, S. Huang, Y. Li, J. Lv, S. Wang and X. Ma, Catal. Sci.
Technol., 2015, 5, 4378–4389.
7 W. D. Michalak, J. M. Krier, S. Alayoglu, J.-Y. Shin, K. An,
K. Komvopoulos, Z. Liu and G. A. Somorjai, J. Catal., 2014,
Chem., 2015, 27, 1293–1298.
1 W. Li, L. Ye, J. Chen, X. Duan, H. Lin and Y. Yuan, Catal.
Today, 2015, 251, 53–59.
2 S. Zhang, X. Duan, L. Ye, H. Lin, Z. Xie and Y. Yuan, Catal.
Today, 2013, 215, 260–266.
3 K. Zhang, H. Zhang, H. Ma, W. Ying and D. Fang, Catal. Lett.,
3
12, 17–25.
8 R. Alcal ´a , M. Mavrikakis and J. A. Dumesic, J. Catal., 2003,
18, 178–190.
3
3
4
4
2
2014, 144, 691–701.
9 Y. H. Li, C. Topf, X. J. Cui, K. Junge and M. Beller, Angew.
Chem., Int. Ed., 2015, 54, 5196–5200.
0 Y. Takeda, Y. Nakagawa and K. Tomishige, Catal.
Sci.Technol., 2012, 2, 2221–2223.
1 J. H. Kim, S. M. Choi, S. H. Nam, M. H. Seo, S. H. Choi and
W. B. Kim, Appl. Catal., B, 2008, 82, 89–102.
2 W. Rachmady and M. A. Vannice, J. Catal., 2002, 209, 87–98.
3 T. Sato, K. Okaya, K. Kunimatsu, H. Yano, M. Watanabe and
H. Uchida, ACS Catal., 2012, 2, 450–455.
4 M. Bonne, M. Haneda, D. Duprez and M. Ozawa, Catal.
Commun., 2012, 19, 74–79.
5 H. Zhu, D. H. Anjum, Q. Wang, E. Abou-Hamad, L. Emsley,
H. Dong, P. Laveille, L. Li, A. K. Samal and J.-M. Basset, J.
Catal., 2014, 320, 52–62.
4 G. C. Torres, S. D. Ledesma, E. L. Jablonski, S. R. de Miguel
and O. A. Scelza, Catal. Today, 1999, 48, 65–72.
5 J. L. Margitfalvi, G. Vank ´o , I. Borb ´a th, A. Tompos and
A. V ´e rtes, J. Catal., 2000, 190, 474–477.
6 C. V ´e rtes, E. T ´a las, I. Czak ´o -Nagy, J. Ryczkowski, S. G ¨o b ¨o l ¨o s,
A. V ´e rtes and J. Margitfalvi, Appl. Catal., 1991, 68, 149–159.
7 Z. Q. Wang, G. Y. Li, X. Y. Liu, Y. Q. Huang, A. Q. Wang, W. Chu,
X. D. Wang and N. Li, Catal. Commun., 2014, 43, 38–41.
8 S. A. Bocanegra, S. R. de Miguel, I. Borbath, J. L. Margitfalvi
and O. A. Scelza, J. Mol. Catal. A: Chem., 2009, 301, 52–60.
9 I. Contreras-Andrade, A. V ´a zquez-Zavala and T. Viveros,
Energy Fuels, 2009, 23, 3835–3841.
4
4
4
4
0 A. K. Medina-Mendoza, M. A. Cort ´e s-J ´a come, J. A. Toledo-
Antonio, C. Angeles-Ch ´a vez, E. L ´o pez-Salinas, I. Cuauht ´e moc-
This journal is © The Royal Society of Chemistry 2016
RSC Adv., 2016, 6, 51005–51013 | 51013