Tetrahedron Letters p. 1085 - 1088 (1990)
Update date:2022-08-29
Topics:
Glass, Timothy E.
Leber, Phyllis A.
Gas-phase pyrolysis of theendo-vinyl epimer (1A) of the title compound at 275°C affords predominantly 3-(2-methyl-2-butenyl)cyclopentene (presumably the Z isomer), a direct [1,5]-hydrogen shift product, whereas the exo-vinyl epimer (IB) favors the fragmentation products, cyclopentene and isoprene.
View MoreDoi:10.1039/c6ta01317a
(2016)Doi:10.3109/10242422.2012.702269
(2012)Doi:10.1007/BF00758856
()Doi:10.1021/ja00235a054
(1987)Doi:10.1002/chem.201403297
(2014)Doi:10.1016/j.tetlet.2012.09.111
(2012)