Journal of the American Chemical Society p. 5475 - 5479 (1981)
Update date:2022-08-17
Topics:
Root, Karen S.
Deutch, John
Whitesides, George M.
Careful studies of the dependence of the rate of reaction (k) of cyclopentyl bromide in diethyl ether with the surface of rotating disk as a function of the angular lelocity (ω) of the disk confirm the relation k * ω1/2 expected for a mass-transfer limited reaction.More limited studies also indicate that the variations in this rate with other parameters are compatible with those expected for a mass-transfer limited reaction: k * (η)-5/6(ρ)1/6 (η is the shear viscosity of the solution and ρ is its density); k * D2/3 (D is the diffusion coefficient of the alkyl halide).
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