Inorganic Chemistry
Communication
ACKNOWLEDGMENTS
J.L.B. and C.A.B. thank the NSF for support (Grants CHE
545138 and 0750413, respectively). M.M.K. thanks the
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Clemson University Chemistry Department for a fellowship
and Carolyn Quarles for performing the ESI-MS experiments.
REFERENCES
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Figure 4. (A) Reaction of [Tpm*Cu(L)] (L = dmise or dmit) with
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3
distorted tetrahedral geometry, bound in a κ fashion to three
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15
(
NCCH ) complex.
3
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atoms, cleavage of the CSe or CS bond, and dimethylimi-
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mediated damage may be prevented in vivo by coordination to
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protection could be an important target for the treatment of
diseases caused by oxidative stress.
́
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Belderrain, T. R.; Per
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ASSOCIATED CONTENT
Supporting Information
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Okamoto, K.; Lehnert, N. Inorg. Chem. 2006, 45, 1698−1713.
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X-ray crystallographic data in CIF format, experimental details,
H and C{ H} NMR spectra of dmise and dmit titrations with
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1
2
2
AUTHOR INFORMATION
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Notes
The authors declare no competing financial interest.
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dx.doi.org/10.1021/ic401366c | Inorg. Chem. XXXX, XXX, XXX−XXX