Tetrahedron p. 2469 - 2476 (1993)
Update date:2022-08-11
Topics:
Mulliez, Michel
Naudy, Carole
α-hydroxysulfinates 1 (table 1) are synthesized (path b, Fig. 1), by slowly adding aldehydes 3 to the mixture sodium dithionite 4 - sodium hydroxide.Owing to their limited stability the products 1 are readily separated from sodium sulfite 5 and isolated.They are easily distinguished (table 2) from their oxydation counterparts 2.
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