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Figure 10. Recycling of the catalyst for epoxidation of cis-cyclooctene
(2 mmol), oxygen balloon (1 atm) and isobutyraldehyde (5 mmol) in 3 ml
of CH3CN catalysed by heterogeneous Mn(III) complex (0. 01 g) at 25 °C for
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Conclusions
The covalent attachment of Mn(III)–salan complex on the GFC
nanocomposite was achieved via a stepwise procedure and the
system was screened as a heterogeneous catalyst for the aerobic
epoxidation of olefins. GFC–[Mn(salan)Cl] exhibited up to 98%
conversion of olefins and up to 100% selectivity to the olefin oxide
upon using air as the oxidizing agent. This material can be easily
recovered by simple magnetic separation and showed good
recoverability with negligible loss in activity and selectivity with
successive runs. The activity of the Mn–salan supported on GFC
composite was higher than that of the homogeneous one due to
the synergic effect of graphene. Most importantly, GFC–[Mn
(salan)Cl] is a green and simple catalytic system in olefin
epoxidation.
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Acknowledgement
The authors thank the University of Zanjan for the financial support
of this study.
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Appl. Organometal. Chem. (2016)
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