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ARTICLE
Journal Name
oxide-supported VO
x
catalyst. However, because the VO
x
15.
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species are tightly incorporated into the MOF as nodes
channels, these species are resistant to leaching. This work also
finds that these catalysts are active in the gas phase oxidation
1
1
1
6.
7.
8.
2 2
of cyclohexene with H O and that the frameworks remain
1
459.
intact even under these conditions. At the higher temperature
gas-phase conditions, saturated oxygenates (cyclohexanone
and diol) dominate, whereas allylic oxidation products
S. Ahn, N. E. Thornburg, Z. Li, T. C. Wang, L. C. Gallington,
K. W. Chapman, J. M. Notestein, J. T. Hupp and O. K. Farha,
Inorganic chemistry, 2016, 55, 11954-11961.
(cyclohexenol and cyclohexenone) dominate at lower
K. Leus, I. Muylaert, M. Vandichel, G. B. Marin, M.
Waroquier, V. Van Speybroeck and P. Van Der Voort,
Chemical Communications, 2010, 46, 5085-5087.
temperatures. Further studies in the gas phase will seek to
understand the particular roles played by the absence of
reaction solvent as well as the higher reaction temperature. This 19.
work can potentially help better understanding of alkene
epoxidation in the liquid- and gas-phase over unconventional
catalysts like catalytic node MOFs.
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Conflicts of interest
There are no conflicts to declare.
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Y.-S. Bae, A. O. z. r. Yazaydın and R. Q. Snurr, Langmuir,
2010, 26, 5475-5483.
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Acknowledgements
The authors gratefully acknowledge the financial support from
the Inorganometallic Catalyst Design Center, an EFRC funded by
the DOE, Office of Basic Energy Sciences (DESC0012702). This
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work was also supported by the National Research Foundation 25.
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