Journal of Chemical Crystallography p. 481 - 486 (2006)
Update date:2022-08-17
Topics:
He, Guang-Yu
Bei, Feng-Li
Chen, Hai-Qun
Sun, Xiao-Qiang
The complex Mo(Et2dtc)2 [Et2dtc: bis(diethyldithiocarbamate)] was synthesized by solid-phase reaction at room temperature and characterized by elemental analysis, powder XRD, IR, 1H NMR and TG/DTA. Its crystal structure was determined by X-ray single crystal diffraction. The crystals are monoclinic with space group P2 1/c, a=0.61800(12)nm; b=1.1540(2)nm; c=1.1610(2)nm; β=95.78(3)°; V=0.8238(3)nm3; D c=1.582g/cm 3; Z=2 F(000)=400; μ=1.285mm-1; R=0.0703; wR=0.2330; GOF=1.060. The coordination geometry of Mo atom, by four S anions from Et 2dtc ligand, is that of a slightly distorted planar square. Furthermore, the optimized geometry, charge distribution, and thermodynamic functions were calculated by quantum chemical method.
View MoreNIGNXIA XINDACHANG TECHNOLOGY CO.,LTD
website:https://xdcchemical.com/
Contact:86-311-85758226
Address:North Industry Area, Wuji
Hubei Sky Lake Chemical Co., Ltd.
Contact:+86-27-87385545
Address:Te-2, Xijiao Chemical Park, Yuekou Town, Tianmen, Hubei, China.
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd
Contact:028-85317716
Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Doi:10.1039/b107567p
(2001)Doi:10.1021/ja01856a506
(1941)Doi:10.1016/j.poly.2014.07.007
(2014)Doi:10.1246/bcsj.59.2577
(1986)Doi:10.1111/j.1744-7976.2001.tb00293.x
(1918)Doi:10.1016/j.bmcl.2018.02.004
(2018)